An Introduction to Chromatography

Chromatography is a term which may refer to anyused to provide a measurement of the concentration
number of different methods of separating theof components of the sample being tested. This
different components of analytes for preparative ormethod may also be used to find out if a given
analytical applications. While the particulars of each ofanalyte is in fact present in a sample at all. While their
type of chromatographic process vary, essentiallyaims may differ, preparative and analytical
what happens is this: an analyte or mixture containingchromatography may in fact be performed in a single
an analyte is combined with a solvent to form a liquidoperation.
or gas (or supercritical fluid in some cases) known asThe most familiar chromatographic testing to most
the mobile phase. The mobile phase is then passedpeople is the columnar method, though paper (which
through a medium fixed in place called,relies on the different rates at which materials bond
understandably enough, the stationary phase; thiswith a sheet of cellulose), planar and thin layer (which
material is often silica, but varies depending on theboth often use a sheet of glass as a substrate
type of chromatography being performed.underneath a layer of silica or cellulose)
The differing physical or chemical properties of thechromatographic methods are also common. There
constituent components of the mobile phase causeare in fact many different methods available, with
them to pass through the stationary phase atsome being better suited to specific applications or
different rates; a process which separates thedifferent analytes. The state and type of analyte to
analyte from the other components of the mobilebe tested for and the purpose of the separation
phase. These different partition coefficients, as theylargely determine whether liquid or gas
are known, are the basis for chromatographicchromatography and which particular type is
preparation and analysis in the laboratory. Essentially,appropriate.
the less affinity which a given component in theThese technologies are useful not only in research
mobile phase has for the material of the stationarylaboratories but are also extensively used in the
phase, the more quickly it will pass through theproduction of chemicals and biotechnology products,
column. It's a bit more complicated than all that, ofwhere it is most commonly used as a separation and
course, but this is the general principle behindpurification method. The precision which the
chromatography.chromatographic process allows for the separation of
In preparative chromatographic applications, the ideaeven the most complex of mixtures where the
is to separate the constituents of the mobile phase,constituents have only the minutest variation.
which are then often put to use elsewhere in theProvided the proper solvent and the proper medium
laboratory. It can be an efficient purification processas the stationary phase, virtually any mixture which is
with certain materials and may be done in nearly anysoluble can be separated this way, making
quantity as needed. Analytical applications, on thechromatography one of the most common
other hand, are usually performed using much smallerprocedures in laboratories.
volumes of material, with the chromatograph being